化工社化工社 化学情報印刷レポート · 研究参考用
Allyl bromide → Diethyl allylphosphonate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Allyl bromide | HCID 7841 | — |
| 反応物 | Triethyl phosphite | HCID 31215 | — |
| 生成物 | Diethyl allylphosphonate | HCID 573014 | — |
反応手順
Allyl bromide was treated with triethylphosphite in the absence of solvent using microwave conditions at 150° C. to give diethyl allylphosphonate. Diethyl allylphosphonate was combined with bromotrimethyl silane and subsequently quenched with methanol to afford diethyl allylphosphonic acid according to Scheme 7.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09234985B2 |
| 出典データセット | uspto-grants-2016_01 |
| ORD ID | ord-0e82b32ecb924645bc132c8becf71036 |
| 出典メモ | uspto-grants-2016_01 |