関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Chlorobutanol | HCID 5977 | — |
| 反応物 | Methyl 2-chloro-2-methylpropanoate | HCID 211144 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | Methacrylic Acid | HCID 4093 | — |
| 生成物 | Methyl Methacrylate | HCID 6658 | — |
| 生成物 | (1,1,1-Trichloro-2-methyl-2-propyl) methacrylate | HCID 118163057 | — |
| 生成物 | (1,1,1-Trichloro-2-methyl-2-propyl) 2-chloro-2-methylpropanoate | HCID 118163068 | — |
反応手順
To 2.83 g of the crude reaction solution obtained was added 0.11 g of methanol, followed by heating at 60° C. for 4 hours. Then, it was found out by gas chromatography analysis that the conversion of the 1,1,1-trichloro-2-methyl-2-propanol was 86.0% and the yield of methyl 2-chloro-2-methylpropanoate was 10.2%. As to other products, it was obtained methyl methacrylate in a 0.2% yield, methacrylic acid in a 8.7% yield, (1,1,1-trichloro-2-methyl-2-propyl) methacrylate in a 13.1% yield, and (1,1,1-trichloro-2-methyl-2-propyl) 2-chloro-2-methylpropanoate in a 22.8% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US09238612B2 |
|---|
| 出典データセット | uspto-grants-2016_01 |
|---|
| ORD ID | ord-77e6c5fd78e34424b45ba1d920c490c3 |
|---|
| 出典メモ | uspto-grants-2016_01 |
|---|
