Oxygen → 2-t-Butylazo-2-hydroperoxy-4-methoxy-4-methylpentane

HRID 596141

反応式

HRID 596141 の反応式
[O:1]1[CH2:6]OOOO1.O=O.[C:9]([N:13]=[N:14][C:15]([O:21][OH:22])([CH2:17][CH:18]([CH3:20])[CH3:19])[CH3:16])([CH3:12])([CH3:11])[CH3:10]>>[C:9]([N:13]=[N:14][C:15]([O:21][OH:22])([CH2:17][C:18]([O:1][CH3:6])([CH3:19])[CH3:20])[CH3:16])([CH3:10])([CH3:12])[CH3:11]

参加物

4

反応物 3

HCID 977OxygenHCID 234664402-[(E)-tert-Butyldiazenyl]-4-methylpentane-2-peroxolHCID 53969305Pentoxane

生成物 1

HCID 213939872-t-Butylazo-2-hydroperoxy-4-methoxy-4-methylpentane

反応条件

温度
0 °C

実験手順

A solution of 60 grams of the t-butylhydrazone of pentoxane (4-methoxy-4-methyl-pentanone-2) in 60 grams of odorless mineral spirits was oxidized by passing oxygen through the solution as in Example II. The oxidation was initiated at 30° C by adding 2 drops of a 50% solution of 2-t-butylazo-2-hydroperoxy-4-methylpentane. The oxidation was 1/2 complete after 50 minutes at 30° C. The temperature was lowered to 20° C. and an additional 1 hour was required before the oxidation was complete. It was then cooled to 0° C. by circulating ice water through the jacket and weighed into a cold poly bottle and stored at -30° C. or below. The yield was 126 g (97% of theory). The solution is not sensitive to shock.

後処理

  1. customwas initiated at 30° C
  2. customcomplete after 50 minutes
  3. customat 30° C
  4. customstored at -30° C. or below

出典と根拠

ORDレコード
ord-8d35f088624b472a9a0b7b5fd7042402
出典データセット
uspto-grants-1977_03
特許番号
US04010152

関連ノート

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