5-Nitro-1-propyl-1H-imidazole → 2-Hydroxymethyl-1-methyl-5-nitroimidazole

HRID 596202

反応式

HRID 596202 の反応式
C(N1C([N+]([O-])=O)=CN=C1)C.C(N1C([N+]([O-])=O)=CN=C1)CC.C(N1C([N+]([O-])=O)=CN=C1)CCC.[CH2:34]([N:36]1[C:40]([N+:41]([O-:43])=[O:42])=[CH:39][N:38]=[C:37]1[CH2:44][OH:45])C.C(N1C([N+]([O-])=O)=CN=C1CO)CC.C(N1C([N+]([O-])=O)=CN=C1CO)CCC.OCC1NC([N+]([O-])=O)=CN=1>>[CH3:34][N:36]1[C:40]([N+:41]([O-:43])=[O:42])=[CH:39][N:38]=[C:37]1[CH2:44][OH:45]

参加物

8

反応物 7

HCID 203624565-Nitro-1-propyl-1H-imidazoleHCID 203624591-n-Butyl-2-hydroxymethyl-5-nitroimidazoleHCID 203624611-Ethyl-2-hydroxymethyl-5-nitroimidazoleHCID 203624791-Propyl-2-hydroxymethyl-5-nitroimidazoleHCID 203624801-Ethyl-5-nitro-1H-imidazoleHCID 203624814-Nitro-1H-imidazole-2-methanolHCID 538551561-n-Butyl-5-nitroimidazole

生成物 1

HCID 5573562-Hydroxymethyl-1-methyl-5-nitroimidazole

実験手順

When 1-ethyl-5-nitroimidazole, 1-propyl-5-nitroimidazole, 1-n-butyl-5-nitroimidazole, and 4(5)-nitroimidazole are used in the above reaction, respectively, the following compounds are prepared: 1-ethyl-2-hydroxymethyl-5-nitroimidazole; 1-propyl-2-hydroxymethyl-5-nitroimidazole; 1-n-butyl-2-hydroxymethyl-5-nitroimidazole; and 2-hydroxymethyl-5-nitroimidazole.

後処理

  1. customrespectively, the following compounds are prepared

出典と根拠

ORDレコード
ord-b7d7ad5d7b204c19873205fedf681ac9
出典データセット
uspto-grants-1977_03
特許番号
US04010176

関連ノート

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