Dimethyldithiocarbamic acid, dimethylamine → 2-Chloro-5-nitro-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

HRID 596503ノート

反応式

HRID 596503 の反応式
[Cl:1][C:2]1[CH:12]=[CH:11][C:10]([N+:13]([O-:15])=[O:14])=[CH:9][C:3]=1[CH:4]=[CH:5][N+:6]([O-:8])=[O:7].[CH3:16][N:17]([CH3:21])[C:18](=[S:20])[S-:19].C[NH2+]C>C(=S)=S>[CH3:16][N:17]([CH3:21])[C:18](=[S:19])[S:20][CH:4]([CH2:5][N+:6]([O-:8])=[O:7])[C:3]1[CH:9]=[C:10]([N+:13]([O-:15])=[O:14])[CH:11]=[CH:12][C:2]=1[Cl:1]

参加物

4

反応物 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 5375673215851-93-1

生成物 1

HCID 213245882-Chloro-5-nitro-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

試薬・触媒・溶媒 1

HCID 6348Carbon Disulfide溶媒

実験手順

As in Example 17, reaction of 2-chloro-β,5-dinitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 2-chloro-5-nitro-α-(nitromethyl)-benzyl dimethyldithiocarbamate melting at 120° C.-121° C. after recrystallization without heating from acetone-methanol solution.

出典と根拠

ORDレコード
ord-614454d9fd4041c18605d95cd2de7dae
出典データセット
uspto-grants-1977_03
特許番号
US04011230

反応ノート

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