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Thionyl Chloride → p-Tetradecyloxyphenylacetylchloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Thionyl Chloride | HCID 24386 | — |
| 反応物 | p-Tetradecyloxyphenylacetic acid | HCID 10472964 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 生成物 | p-Tetradecyloxyphenylacetylchloride | HCID 10021844 | — |
反応手順
A solution of 10.0 g. p-tetradecyloxyphenylacetic acid in 100 ml. absolute benzene is treated with 19.9 g thionylchloride and refluxed for 2.5 hours. The reaction mixture is then evaporated under vacuum (i.v.) and azeotroped several times with benzene to remove residual thionylchloride, to obtain crude p-tetradecyloxyphenylacetylchloride, which may be used in Step E, below, without further refining.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04011339 |
| 出典データセット | uspto-grants-1977_03 |
| ORD ID | ord-5e97ab17b6eb4490a02e2bd78e3b8f55 |
| 出典メモ | uspto-grants-1977_03 |