化工社化工社 化学情報印刷レポート · 研究参考用
Cyclopentadiene → 826-62-0
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Cyclopentadiene | HCID 7612 | — |
| 反応物 | Maleic Anhydride | HCID 7923 | — |
| 生成物 | 826-62-0 | HCID 13223 | 25% |
反応手順
The Diels-Alder adduct from cyclopentadiene and maleic anhydride, endo-cis-5-norbornene-2,3-dicarboxylic anhydride, m.p. 165° C., was heated at 220° C. for 4 hours. On cooling the product solidified with a melting point of 101° C. The crude reaction product was recrystallized from benzene three times to isolate exo-cis-5-norbornene-2,3-dicarboxylic anhydride, m.p. 141° C., in 25% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04012575 |
| 出典データセット | uspto-grants-1977_03 |
| ORD ID | ord-3c08400b4abe4e1789bd3fdee1e4e9a6 |
| 出典メモ | uspto-grants-1977_03 |