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p-Toluenesulfonic acid → 1-Hydroxy-2-cyclopentyltetraline
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | p-Toluenesulfonic acid | HCID 6101 | — |
| 反応物 | Cyclopentene | HCID 8882 | — |
| 反応物 | 1,2,3,4-Tetrahydro-1-naphthalenol | HCID 10723 | — |
| 生成物 | 1-Hydroxy-2-cyclopentyltetraline | HCID 21446501 | — |
反応手順
40 g of cyclopentene are added dropwise at 120° C to 148 g of 1-hydroxytetraline and 10 g of p-toluene sulphonic acid. The catalyst is removed by washing with sodium hydrogen carbonate solution. The reaction mixture is fractionated. At 161° C (2 mm Hg) 58 g of 1-hydroxy-2-cyclopentyltetraline are obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04013473 |
| 出典データセット | uspto-grants-1977_03 |
| ORD ID | ord-70f6c25426584fe8b20a2d854275c8fa |
| 出典メモ | uspto-grants-1977_03 |