Phenetole → 2-Methoxy-5-methylphenol

反応式

C([O:3]C1C=CC=CC=1)C.[CH3:10][O:11][C:12]1[CH:17]=[CH:16][C:15]([CH3:18])=[CH:14][CH:13]=1>>[CH3:10][O:11][C:12]1[CH:17]=[CH:16][C:15]([CH3:18])=[CH:14][C:13]=1[OH:3]

参加物

反応物 2

HCID 7674Phenetole

HCID 77314-Methylanisole

生成物 1

HCID 145192-Methoxy-5-methylphenol収率 46.9%

実験手順

The reaction was carried out in the same manner as in Example 6 except that ethoxybenzene was replaced by 150 g. (1229.5 m.moles) of p-methoxytoluene and 4.11 g. (29.8 m.moles) of 2-methoxy-5-methylphenol was obtained in a yield of 46.9 %.

出典と根拠

ORDレコード: ord-16ee44319c6f4016bc01328e5f35cb28
出典データセット: uspto-grants-1977_03
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04013727

反応ノート

読み込み中…