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4-Chlorophenyl Isocyanate → methyl 4-(p-chlorophenyl)-N-methoxycarbonylallophanimidate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 4-Chlorophenyl Isocyanate | HCID 7693 | — |
| 反応物 | 1-methoxycarbonyl-S-methylisothiourea | HCID 293578 | — |
| 反応物 | N-carbomethoxy-O-methylisourea | HCID 53429793 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | methyl 4-(p-chlorophenyl)-N-methoxycarbonylallophanimidate | HCID 54018948 | — |
反応手順
To 13 parts of methyl N-(1-amino-1-methoxymethylene)-carbamate, m.p. 36°-39.5°, prepared similar to the procedure in Example 3 for methyl N-(1-amino-1-methylthiomethylene)-carbamate in 140 parts of methylene chloride is added 15 parts of p-chlorophenyl isocyanate. The reaction mixture is stirred overnight and the solution filtered to give 10 parts of methyl 4-(p-chlorophenyl)-N-methoxycarbonylallophanimidate melting at 170° dec.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04014924 |
| 出典データセット | uspto-grants-1977_03 |
| ORD ID | ord-70ff63c298bc4898ad7d5f35496eca79 |
| 出典メモ | uspto-grants-1977_03 |