Hexanal → HCID 86744107、化合物

HRID 597702ノート

反応式

HRID 597702 の反応式
C([Li:5])C[CH2:3][CH3:4].[CH:6]([N-:9][CH:10]([CH3:12])[CH3:11])([CH3:8])[CH3:7].[CH3:13][C:14](C)([O-:16])C.[K+].C(=O)CCCCC>CCCCCC.CCOCC>[CH:6]([N-:9][CH:10]([CH3:12])[CH3:11])([CH3:8])[CH3:7].[Li+:5].[CH3:13][CH2:14][O:16][CH2:3][CH3:4]

参加物

7

反応物 4

HCID 6184HexanalHCID 5062348DiisopropylamideHCID 23665647Potassium tert-butoxideHCID 178418339Butyllithium

生成物 1

HCID 86744107HCID 86744107、化合物

試薬・触媒・溶媒 2

HCID 3283Diethyl Ether溶媒HCID 8058Hexane溶媒

実験手順

67 ml (0.11 M) of a 1.6 N solution of butyllithium in hexane were treated at 0° with 11.1 g (0.11 M) of diisopropylamide, and the reaction mixture was kept at 0° under stirring during 30 min. To this reaction mixture there was then added 1 g of potassium ter-butoxide followed by 24.5 g (0.05 M) of 4-bromo-pent-2trans-en-1-yl triphenylphosphonium bromide and the mixture obtained was kept under stirring during 18 h at 23°, whereupon a solution of 5 g (0.05 M) of hexanal in 35 ml of anhydrous ether at 8°-15° was added thereto.

後処理

  1. customwas kept at 0°
  2. customthe mixture obtained
  3. additionwas added

出典と根拠

ORDレコード
ord-bac2df751a0d4aa2b94abf05db3b4053
出典データセット
uspto-grants-1977_03
特許番号
US04014951

反応ノート

読み込み中…