Sulfanium bromide → Sulfonium perfluorobutane sulfonate

HRID 597756ノート

反応式

HRID 597756 の反応式
[Br-].[SH3+:2].[F:3][C:4]([F:19])([S:15]([O-:18])(=[O:17])=[O:16])[C:5]([F:14])([F:13])[C:6]([F:12])([F:11])[C:7]([F:10])([F:9])[F:8].[Na+]>[N+](C)([O-])=O>[F:19][C:4]([F:3])([S:15]([O-:18])(=[O:17])=[O:16])[C:5]([F:13])([F:14])[C:6]([F:12])([F:11])[C:7]([F:10])([F:9])[F:8].[SH3+:2]

参加物

4

反応物 2

HCID 23498378Sulfanium bromideHCID 23678450Sodium perfluorobutanesulfonate

生成物 1

HCID 22483813Sulfonium perfluorobutane sulfonate

試薬・触媒・溶媒 1

HCID 6375Nitromethane溶媒

実験手順

The thus obtained monomer precursor is mixed with, for example, phenacyl bromide in acetonitrile or nitromethan at room temperature, to thereby obtain the corresponding sulfonium bromide. With the thus obtained sulfonium bromide, for example, sodium perfluorobutane sulfonate is mixed in nitromethane at room temperature to thereby obtain the targeted product of sulfonium perfluorobutane sulfonate. Moreover, the thus obtained sulfonium perfluorobutanesulfonate can be further purified by recrystallization.

出典と根拠

ORDレコード
ord-b7f149b3e99a4d5aabb5b4e532189636
出典データセット
uspto-grants-2011_03
特許番号
US07897321B2

反応ノート

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