化工社化工社 化学情報印刷レポート · 研究参考用
Oxygen → 4-Phenyl-3-Buten-2-one
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oxygen | HCID 977 | — |
| 反応物 | 4-Phenylbut-3-en-2-ol | HCID 15172 | — |
| 触媒 | Platinum | HCID 23939 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 4-Phenyl-3-Buten-2-one | HCID 15909 | 87.5% |
反応手順
In an ambient pressure oxygen atmosphere, 29.2 mg of 4-phenyl-but-3-ene-2-ol and 33.9 mg of the platinum catalyst obtained in Example 1 were agitated for fifteen hours at 60° C. in 2 ml of water. The reaction mixture was subsequently extracted using ethyl acetate, and the organic layer was dried using magnesium sulfate, filtered and concentrated to obtain 25.2 mg (87% yield) of benzalacetone. The reaction equation and the analytical results of the product are shown below.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07897817B2 |
| 出典データセット | uspto-grants-2011_03 |
| ORD ID | ord-441a9e81c2ae40b4b5312c7d92167e28 |
| 出典メモ | uspto-grants-2011_03 |