Acetic Acid → Benzoic acid, 4-nitro-, 2-ethylhexyl ester

HRID 600160

反応式

HRID 600160 の反応式
S1C(C=[O:7])=CC=C1C=O.C(O)(=O)C.[CH2:14]([CH:16]([CH2:29][CH2:30][CH2:31][CH3:32])[CH2:17][O:18][C:19](=[O:28])[C:20]1[CH:25]=[CH:24][C:23]([NH:26][OH:27])=[CH:22][CH:21]=1)[CH3:15]>O>[CH2:14]([CH:16]([CH2:29][CH2:30][CH2:31][CH3:32])[CH2:17][O:18][C:19](=[O:28])[C:20]1[CH:21]=[CH:22][C:23]([N+:26]([O-:7])=[O:27])=[CH:24][CH:25]=1)[CH3:15]

参加物

5

反応物 3

HCID 176Acetic AcidHCID 587784Thiophene-2,5-dicarbaldehydeHCID 576239434-Hydroxyamino-Benzoic Acid 2-Ethyl-Hexyl Ester

生成物 1

HCID 591313Benzoic acid, 4-nitro-, 2-ethylhexyl ester収率 160.6%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

To a 250 ml 3-necked flask was added 0.5 gm 2,5-thiophenedicarboxaldehyde, 30 ml acetic acid, 5.6 gm 2-ethylhexylesterphenyl hydroxylamine 3 and stirred for 20 hrs at room temperature. To the reaction mixture, 100 ml water was added and the mixture was filtered. The filtered product was washed with water and dried. A yield of about 1.6 gm of 2, 5-thiophene bis-2-ethylhexylesterphenyl dinitrone of Ex.2 was obtained with a HPLC purity of 98% (DSC: 205° C.).

後処理

  1. filtrationthe mixture was filtered
  2. washThe filtered product was washed with water
  3. customdried

出典と根拠

ORDレコード
ord-fa8bbf3d1c784c80b2f1aac4bd852d51
出典データセット
uspto-grants-2011_03
特許番号
US07901839B2

関連ノート

読み込み中…