3-Bromoaniline → N-(3-bromophenyl)-4-chloro-3-nitrobenzamide

反応式

[Cl:1][C:2]1[CH:10]=[CH:9][C:5]([C:6](Cl)=[O:7])=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12].[Br:14][C:15]1[CH:16]=[C:17]([NH2:21])[CH:18]=[CH:19][CH:20]=1>>[Br:14][C:15]1[CH:16]=[C:17]([NH:21][C:6](=[O:7])[C:5]2[CH:9]=[CH:10][C:2]([Cl:1])=[C:3]([N+:11]([O-:13])=[O:12])[CH:4]=2)[CH:18]=[CH:19][CH:20]=1

参加物

反応物 2

HCID 115623-Bromoaniline

HCID 1234774-Chloro-3-nitrobenzoyl chloride

生成物 1

HCID 1368133N-(3-bromophenyl)-4-chloro-3-nitrobenzamide

実験手順

A mixture of 4-chloro-3-nitrobenzoyl chloride was reacted with 3-Bromo-phenylamine to produce N-(3-Bromo-phenyl)-4-chloro-3-nitro-benzamide according to the procedure of Example 10A, which was treated sequentially using the procedures from Examples 13A, 13B and 13C to provide the title product.

出典と根拠

ORDレコード: ord-7199aa0803f1432d88b9269241ddffef
出典データセット: uspto-grants-2011_03
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07910595B2

反応ノート

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