Hydroquinone → 4-[2-Amino-4-(4-bromo-benzyloxy)-phenoxy]-phenol

反応式

[Br:1][C:2]1[CH:19]=[CH:18][C:5]([CH2:6][O:7][C:8]2[CH:13]=[CH:12][C:11](Cl)=[C:10]([N+:15]([O-])=O)[CH:9]=2)=[CH:4][CH:3]=1.[C:20]1([CH:27]=[CH:26][C:24]([OH:25])=[CH:23][CH:22]=1)[OH:21]>>[NH2:15][C:10]1[CH:9]=[C:8]([O:7][CH2:6][C:5]2[CH:18]=[CH:19][C:2]([Br:1])=[CH:3][CH:4]=2)[CH:13]=[CH:12][C:11]=1[O:21][C:20]1[CH:27]=[CH:26][C:24]([OH:25])=[CH:23][CH:22]=1

参加物

反応物 2

HCID 785Hydroquinone

HCID 574698834-(4-Bromo-benzyloxy)-1-chloro-2-nitro-benzene

生成物 1

HCID 668085674-[2-Amino-4-(4-bromo-benzyloxy)-phenoxy]-phenol

実験手順

4-(4-Bromo-benzyloxy)-1-chloro-2-nitro-benzene (from Example 16A) was reacted with hydroquinone according to the procedure from Example 39A and reduced according to the procedure from Example 39B to provide the title product.

出典と根拠

ORDレコード: ord-70139d9f0f56406b84ad765ca809e475
出典データセット: uspto-grants-2011_03
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07915411B2

反応ノート

読み込み中…