Cyclohexane-1,1-dicarboxylic acid → Cyclohexane dicarboxylic acid molybdenum

HRID 610744

反応式

HRID 610744 の反応式
[C:1]1([C:10]([OH:12])=[O:11])([C:7]([OH:9])=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C([O-])(=O)C.[Mo+4:17].C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C>CO>[Mo:17].[C:1]1([C:10]([OH:12])=[O:11])([C:7]([OH:9])=[O:8])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]1

参加物

4

反応物 2

HCID 136906Cyclohexane-1,1-dicarboxylic acidHCID 11473018Molybdenum acetate

生成物 1

HCID 88023834Cyclohexane dicarboxylic acid molybdenum

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

0.885 g (5.14 mmol) of cyclohexane dicarboxylic acid and 1,000 g (2.34 mmol) of molybdenum acetate were dissolved in 900 ml of methanol. After this was stirred for three days at the room temperature, this was kept still for a few days. Thereafter, its precipitation product was suction-filtered, rinsed sufficiently with methanol and then vacuum-dried for 60° C./4 hours, whereby 1.216 g of target substance was obtained. This substance had the specific surface area of 212 m2 /g. And, a measurement according to the HK method using argon revealed that the substance had the pore diameter of 5.2 Å.

後処理

  1. waitthis was kept still for a few days
  2. customThereafter, its precipitation product
  3. filtrationwas suction-filtered
  4. washrinsed sufficiently with methanol
  5. customvacuum-dried for 60° C./4 hours, whereby 1.216 g of target substance
  6. customwas obtained

出典と根拠

ORDレコード
ord-96d438c069e0448c99acbd5c2db4799a
出典データセット
uspto-grants-1999_12
特許番号
US05998647

関連ノート

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