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Phenazine → 2,3-dimethylbenzo(B)phenazine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Phenazine | HCID 4757 | — |
| 反応物 | Methyl iodide | HCID 6328 | — |
| 反応物 | 2,3-Diaminonaphthalene | HCID 69872 | — |
| 反応物 | 4,5-Dimethyl-1,2-benzoquinone | HCID 12294704 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 2,3-dimethylbenzo(B)phenazine | HCID 19350146 | — |
反応手順
The 2,3-dimethylbenzo(B)phenazine was prepared by the condensation of 2,3-diaminonapthalene with 4,5-dimethyl-1,2-benzoquinone in 4:1 ethanol to acetic acid at reflux for 2 hours. The phenazine was alkylated by the procedure of Synthesis Example 8, using iodomethane. Electrochemical analysis was consistent with an N,N'-dialkylated phenazine.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05998617 |
| 出典データセット | uspto-grants-1999_12 |
| ORD ID | ord-38d5154dd9e94c729f7719601216679e |
| 出典メモ | uspto-grants-1999_12 |