Benzyl Bromide → 3-Benzyl-2-methyl-1,3-benzothiazol-3-ium bromide
反応式
[CH3:1][C:2]1[S:3][C:4]2[CH:10]=[CH:9][CH:8]=[CH:7][C:5]=2[N:6]=1.[CH2:11]([Br:18])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>C(OCC)(=O)C>[Br-:18].[CH2:11]([N+:6]1[C:5]2[CH:7]=[CH:8][CH:9]=[CH:10][C:4]=2[S:3][C:2]=1[CH3:1])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1参加物
4
実験手順
A solution of 2-methylbenzothiazole (5.0 g, 0.033 mol) and benzyl bromide (40 mL, 0.33 mol) in 250 mL of ethyl acetate was refluxed under nitrogen for 48 hours. Solid had formed. The mixture was filtered and washed with cold ethyl acetate to give 3-benzyl-2-methylbenzothiazol-3-ium bromide as a light yellow solid, mp 230-231° C.
後処理
- customSolid had formed
- filtrationThe mixture was filtered
- washwashed with cold ethyl acetate
出典と根拠
- ORDレコード
- ord-79ed2b70094d4f5d827b3e14d8a7c92e
- 出典データセット
- uspto-grants-1999_12
- 特許番号
- US06001331
反応ノート
読み込み中…