3-Bromo-1,1,2,2-tetrafluoropropane → HCID 178447728、化合物
反応式
Br[C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][C:11]([O:14][Si](C(C)(C)C)(C)C)=[CH:10][CH:9]=2)=[CH:4][CH:3]=1.C([Si:27]1([C:34]2[CH:39]=[CH:38][CH:37]=[CH:36]C=2)[CH2:32][CH2:31][C:30](=O)[CH2:29][CH2:28]1)CCCC.Br[CH2:41][C:42]([F:47])([F:46])[CH:43]([F:45])[F:44]>>[CH2:34]([Si@H:27]1[CH2:28][CH2:29][C@H:30]([C:2]2[CH:3]=[CH:4][C:5]([C:8]3[CH:9]=[CH:10][C:11]([O:14][CH2:41][C:42]([F:47])([F:46])[CH:43]([F:45])[F:44])=[CH:12][CH:13]=3)=[CH:6][CH:7]=2)[CH2:31][CH2:32]1)[CH2:39][CH2:38][CH2:37][CH3:36]参加物
4
実験手順
The general procedure of Example 17 was repeated using 4'-bromo-4-(t-butyldimethylsiloxy)biphenyl, 4-pentyl-4-phenyl-4-silacyclohexanone, and 1-bromo-2,2,3,3-tetrafluoro-n-propane, thereby obtaining the intended compound.
後処理
- customobtaining the intended compound