3-Bromo-1,1,1-trifluoropropane → HCID 178447727、化合物
反応式
Br[C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][C:11]([O:14][Si](C(C)(C)C)(C)C)=[CH:10][CH:9]=2)=[CH:4][CH:3]=1.[CH3:22][CH:23]([CH3:39])[CH2:24][CH2:25][Si:26]1(C2C=CC=CC=2)[CH2:31][CH2:30][C:29](=O)[CH2:28][CH2:27]1.Br[CH2:41][CH2:42][C:43]([F:46])([F:45])[F:44]>>[CH3:39][CH:23]([CH3:22])[CH2:24][CH2:25][Si@H:26]1[CH2:27][CH2:28][C@H:29]([C:2]2[CH:3]=[CH:4][C:5]([C:8]3[CH:9]=[CH:10][C:11]([O:14][CH2:41][CH2:42][C:43]([F:46])([F:45])[F:44])=[CH:12][CH:13]=3)=[CH:6][CH:7]=2)[CH2:30][CH2:31]1参加物
4
実験手順
The general procedure of Example 17 was repeated using 4'-bromo-4-(t-butyldimethylsiloxy)biphenyl, 4-(3-methyl-n-butyl)-4-phenyl-4-silacyclohexanone, and 1-bromo-3,3,3-trifluoro-n-propane, thereby obtaining the intended compound.
後処理
- customobtaining the intended compound