2-Bromo-1,1,1-trifluoroethane → HCID 178447738、化合物

反応式

C([Si:6]1([C:13]2[CH:18]=[CH:17][CH:16]=[CH:15]C=2)[CH2:11][CH2:10][C:9](=O)[CH2:8][CH2:7]1)CCCC.Br[C:20]1[CH:25]=[CH:24][C:23]([O:26][Si](C(C)(C)C)(C)C)=[CH:22][CH:21]=1.Br[CH2:35][C:36]([F:39])([F:38])[F:37]>>[CH2:13]([Si@H:6]1[CH2:7][CH2:8][C@H:9]([C:20]2[CH:21]=[CH:22][C:23]([O:26][CH2:35][C:36]([F:39])([F:38])[F:37])=[CH:24][CH:25]=2)[CH2:10][CH2:11]1)[CH2:18][CH2:17][CH2:16][CH3:15]

参加物

反応物 3

HCID 678982-Bromo-1,1,1-trifluoroethane

HCID 4227167(4-Bromophenoxy)(tert-butyl)dimethylsilane

HCID 110762054-Pentyl-4-phenyl-4-silacyclohexanone

生成物 1

HCID 178447738HCID 178447738、化合物

実験手順

The general procedure of Example 17 was repeated using 4-n-pentyl-4-phenyl-4-silacyclohexanone, 4-bromo-1-(t-butyldimethylsiloxy)benzene and 1-bromo-2,2,2-trifluoroethane, thereby obtaining the intended compound.