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1,2-Benzenedicarboxylic acid, 4-nitro-, 1,2-dimethyl ester → Dimethyl 4-(4-methylphenoxy)phthalate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,2-Benzenedicarboxylic acid, 4-nitro-, 1,2-dimethyl ester | HCID 69119 | — |
| 反応物 | Sodium p-methylphenolate | HCID 23673456 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | Dimethyl 4-(4-methylphenoxy)phthalate | HCID 19595679 | — |
反応手順
Dimethyl 4-nitrophthalate was reacted in DMF with sodium 4-methylphenoxide to give dimethyl 4-(4-methylphenoxy)phthalate in analogy to a process known from the literature (J. Org. Chem. Vol. 42, No. 21, 1977, 3419-3425). After standard working up and chromatography using hexane/EA, the diester was isolated as a yellowish oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06005010 |
| 出典データセット | uspto-grants-1999_12 |
| ORD ID | ord-f90c1636df7f4585930f4d42652aa76d |
| 出典メモ | uspto-grants-1999_12 |