Acrylamide → n-Butylacrylate Acrylamide

HRID 613194

反応式

HRID 613194 の反応式
[Cl-].C[N+](C)(C)CCOC(=O)C=C.[CH2:13]([O:17][C:18](=[O:21])[CH:19]=[CH2:20])[CH2:14][CH2:15][CH3:16].[C:22]([NH2:26])(=[O:25])[CH:23]=[CH2:24]>C(O)(C)C>[CH2:13]([O:17][C:18](=[O:21])[CH:19]=[CH2:20])[CH2:14][CH2:15][CH3:16].[C:22]([NH2:26])(=[O:25])[CH:23]=[CH2:24]

参加物

5

反応物 3

HCID 6579AcrylamideHCID 8846Butyl AcrylateHCID 162071Ethanaminium, N,N,N-trimethyl-2-[(1-oxo-2-propen-1-yl)oxy]-, chloride (1:1)

生成物 1

HCID 86584089n-Butylacrylate Acrylamide

試薬・触媒・溶媒 1

HCID 3776Isopropanol溶媒

反応条件

温度
75 °C

実験手順

To a 500 mL round-bottom, three-neck flask fitted with a thermocouple, reflux condenser, and septum was added 150 mL of isopropanol followed by 16.13 g of a 50% aqueous solution of 2-trimethylammonioethylacrylate chloride, 8.06 g of n-butylacrylate, and 8.06 g of acrylamide. The solution was purged with nitrogen for 1 hour and 0.5 g AIBN was added. The mixture was purged for ~ 15 minutes until all of the AIBN dissolved. The solution was heated to 75° C. under nitrogen for 16 hours.

後処理

  1. customTo a 500 mL round-bottom, three-neck flask fitted with a thermocouple
  2. temperaturereflux condenser
  3. customThe solution was purged with nitrogen for 1 hour
  4. addition0.5 g AIBN was added
  5. customThe mixture was purged for ~ 15 minutes until all of the AIBN
  6. dissolutiondissolved

出典と根拠

ORDレコード
ord-e99a26e464ef4fe0a2722d1b6c2ac432
出典データセット
uspto-grants-1999_12
特許番号
US06007803

関連ノート

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