関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Acrylamide | HCID 6579 | — |
| 反応物 | tert-Butyl acrylate | HCID 15458 | — |
| 反応物 | Ethanaminium, N,N,N-trimethyl-2-[(1-oxo-2-propen-1-yl)oxy]-, chloride (1:1) | HCID 162071 | — |
| 溶媒 | Isopropanol | HCID 3776 | — |
| 生成物 | t-Butylacrylate Acrylamide | HCID 86584091 | — |
反応手順
To a 500 mL round-bottom, three-neck flask fitted with a thermocouple, reflux condenser, and septum was added 150 mL of isopropanol followed by 16.13 g of a 50% aqueous solution of 2-trimethylammonioethylacrylate chloride, 8.06 g of t-butylacrylate, and 8.06 g of acrylamide. The solution was purged with nitrogen for 1 hour and 0.5 g AIBN was added. The mixture was purged for ~ 15 minutes until all of the AIBN dissolved. The solution was heated to 75° C. under nitrogen for 16 hours.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06007803 |
|---|
| 出典データセット | uspto-grants-1999_12 |
|---|
| ORD ID | ord-5a58c62c9040412d84b18bc447c2897b |
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| 出典メモ | uspto-grants-1999_12 |
|---|
