関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Isoprene | HCID 6557 | — |
| 反応物 | 3,4-Dimethyl-2-methylenevaleraldehyde | HCID 3020423 | — |
| 生成物 | 1-(1,2-Dimethyl-propyl)-4-methyl-cyclohex-3-enecarbaldehyde | HCID 89705176 | 49% |
反応手順
3,4-Dimethyl-2-methylene-pentanal (550 g, obtained as detailed above) and 393 g of isoprene were charged to a Parr Bomb, heated to 160° C., and aged for 12 hours. The rushed over material provided ˜32% recovery of 1-(1,2-dimethyl-propyl)-4-methyl-cyclohex-3-enecarbaldehyde (415 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US09441185B2 |
|---|
| 出典データセット | uspto-grants-2016_09 |
|---|
| ORD ID | ord-3203e99590bb4da6b11acc7689d1cedd |
|---|
| 出典メモ | uspto-grants-2016_09 |
|---|
