化工社化工社 化学情報印刷レポート · 研究参考用
3'-Aminoacetophenone → N,N'-bis(3-acetylphenyl)pentanediamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 3'-Aminoacetophenone | HCID 7417 | — |
| 反応物 | Pentanedioyl dichloride | HCID 17887 | — |
| 反応物 | Cni H1894 | HCID 463010 | — |
| 反応物 | HCID 15541276 | HCID 15541276 | — |
| 反応物 | HCID 15541277 | HCID 15541277 | — |
| 反応物 | HCID 15541278 | HCID 15541278 | — |
| 反応物 | HCID 15541279 | HCID 15541279 | — |
| 反応物 | N,N'-bis(3,5-diacetylphenyl)nonanediamide | HCID 15541280 | — |
| 反応物 | N~1~,N~10~-Bis(3,5-diacetylphenyl)decanediamide | HCID 15541281 | — |
| 反応物 | HCID 15541282 | HCID 15541282 | — |
| 生成物 | N,N'-bis(3-acetylphenyl)pentanediamide | HCID 1010291 | — |
反応手順
Analogously, the following were prepared from 3,5-diacetylaniline and the corresponding dioyl dichlorides: N,N'-bis(3,5-diacetylphenyl) butanediamide, mp 293-6° C.; N,N'-bis(3,5-diacetylphenyl)hexanediamide, mp 269-70° C.; N,N'-bis(3,5-diacetylphenyl)heptanediamide, mp 200-3° C.; N,N'-bis(3,5-diacetylphenyl)octanediamide, mp 183-4° C.; N,N'-bis(3,5-diacetylphenyl)nonanediamide, mp 179-80° C.; N,N'-bis(3,5-diacetylphenyl)decanediamide, mp 196-9° C.; N,N'-bis(3,5-diacetylphenyl)dodecanediamide, mp 178-9° C.; N,N'-bis(3,5-diacetylphenyl)(isophthalic acid diamide), mp 283-4° C. Also analogously, N,N'-bis(3-acetylphenyl)pentanediamide, mp 174-5° C. was prepared from 3-aminoacetophenone and glutaryl dichloride.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06008255 |
| 出典データセット | uspto-grants-1999_12 |
| ORD ID | ord-a038a1ede9d14bed9a89ded3b152f9a5 |
| 出典メモ | uspto-grants-1999_12 |