Potassium Cyanide → 4-Ethoxybenzene-1-carbonyl cyanide

HRID 614032ノート

反応式

HRID 614032 の反応式
[CH2:1]([O:3][C:4]1[CH:12]=[CH:11][C:7]([C:8](Cl)=[O:9])=[CH:6][CH:5]=1)[CH3:2].[C-:13]#[N:14].[K+]>[Cu]C#N>[CH2:1]([O:3][C:4]1[CH:12]=[CH:11][C:7]([C:8]([C:13]#[N:14])=[O:9])=[CH:6][CH:5]=1)[CH3:2]

参加物

4

反応物 2

HCID 9032Potassium CyanideHCID 1400594-Ethoxybenzoyl Chloride

生成物 1

HCID 233362744-Ethoxybenzene-1-carbonyl cyanide収率 94.5%

試薬・触媒・溶媒 1

HCID 178418546HCID 178418546、化合物触媒

実験手順

In the manner described above, 184 g (1 mol) of p-ethoxybenzoyl chloride, 62.5 g (0.96 mol) of potassium cyanide and 3.6 g (0.04 mol) of copper(I) cyanide were reacted with one another at 215° C. After working up, 159 g (91% of theory) of p-ethoxybenzoyl cyanide were obtained; melting point 43° C.

後処理

  1. customwere reacted with one another at 215° C

出典と根拠

ORDレコード
ord-7a7d4285c3a8478c8cabc3b9d3f37da6
出典データセット
uspto-grants-1979_03
特許番号
US04143068

反応ノート

読み込み中…