化工社化工社 化学情報印刷レポート · 研究参考用
N,N-Dimethyltetradecylamine → 1-Adamantylcarbonylmethyldimethyltetradecylammonium bromide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | N,N-Dimethyltetradecylamine | HCID 8211 | — |
| 反応物 | Bromomethyl tricyclo[3.3.1.13,7]dec-1-yl ketone | HCID 197820 | — |
| 溶媒 | Acetone | HCID 180 | — |
| 生成物 | 1-Adamantylcarbonylmethyldimethyltetradecylammonium bromide | HCID 86733511 | 84.2% |
反応手順
A mixture of 1.3g. (0.005 mole) 1-adamantyl bromomethyl ketone and 1.23g (0.005 mole) dimethyltetradecylamine was solubilized by the addition of 30cc acetone. The next day the solidified mixture was washed with ether and recrystallized from ethyl acetate to yield 2.1g white crystals, m.p. 134°-135.5°.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04143127 |
| 出典データセット | uspto-grants-1979_03 |
| ORD ID | ord-7f8144f1ac4a41dd89582865bff2707e |
| 出典メモ | uspto-grants-1979_03 |