4-Bromophenylhydrazine → HCID 21329392、化合物

HRID 614386ノート

反応式

HRID 614386 の反応式
[S:1]1(=[O:11])(=[O:10])[CH2:8][CH2:7][CH2:6][C:5](=O)[CH2:4][CH2:3][CH2:2]1.[Br:12][C:13]1[CH:18]=[CH:17][C:16]([NH:19]N)=[CH:15][CH:14]=1>C(O)(=O)C>[Br:12][C:13]1[CH:18]=[CH:17][C:16]2[NH:19][C:5]3[CH2:4][CH2:3][CH2:2][S:1](=[O:11])(=[O:10])[CH2:8][CH2:7][C:6]=3[C:15]=2[CH:14]=1

参加物

4

反応物 2

HCID 121584-BromophenylhydrazineHCID 262584thiocan-5-one 1,1-dioxide

生成物 1

HCID 21329392HCID 21329392、化合物

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

実験手順

A mixture of 14.1g (0.08 mole) of 1-thiacyclooctane-5-one 1,1-dioxide and 16.1g (0.086 mole) of p-bromophenylhydrazine in 125 ml of glacial acetic acid is treated according to the procedure in Example 2. There is obtained 14.2g (54%) of a buff solid, m.p. 280° C., dec. Recrystallization from dimethylformamide-methanol gives 11.5g (44%) of an analytical sample, m.p. 283° C., dec.

後処理

  1. additionis treated
  2. customThere is obtained 14.2g (54%) of a buff solid, m.p. 280° C., dec
  3. customRecrystallization from dimethylformamide-methanol
  4. customgives 11.5g (44%) of an analytical sample, m.p. 283° C., dec.

出典と根拠

ORDレコード
ord-7f85a91c5f594f09b08119784f35cbf8
出典データセット
uspto-grants-1979_03
特許番号
US04144349

反応ノート

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