N-(3-(dimethylamino)propyl)formamide → N,N-dimethyl-N-(4-nitrophenyl)carbamylmethyl-N-3-formamidopropylammonium chloride

HRID 614720

反応式

HRID 614720 の反応式
[CH3:1][N:2]([CH3:9])[CH2:3][CH2:4][CH2:5][NH:6][CH:7]=[O:8].[Cl:10][CH2:11][C:12]([NH:14][C:15]1[CH:20]=[CH:19][C:18]([N+:21]([O-:23])=[O:22])=[CH:17][CH:16]=1)=[O:13]>C(O)(C)C>[Cl-:10].[CH3:1][N+:2]([CH3:9])([CH2:11][C:12](=[O:13])[NH:14][C:15]1[CH:20]=[CH:19][C:18]([N+:21]([O-:23])=[O:22])=[CH:17][CH:16]=1)[CH2:3][CH2:4][CH2:5][NH:6][CH:7]=[O:8]

参加物

4

反応物 2

HCID 80020N-(3-(dimethylamino)propyl)formamideHCID 140220Acetanilide, 2-chloro-4'-nitro-

生成物 1

HCID 86733006N,N-dimethyl-N-(4-nitrophenyl)carbamylmethyl-N-3-formamidopropylammonium chloride

試薬・触媒・溶媒 1

HCID 3776Isopropanol溶媒

実験手順

In a manner similar to that described above in 1a, using 14.2 parts of N-(3-dimethylaminopropyl)formamide, 20.0 parts of 2-chloro-4'-nitroacetanilide, and 78 parts of isopropyl alcohol there was obtained 27.4 parts of N,N-dimethyl-N-(4-nitrophenyl)carbamylmethyl-N-3-formamidopropylammonium chloride as a white solid which melted at 195°-196° C.

出典と根拠

ORDレコード
ord-96a813102ea743aeb9ca669c96a5465a
出典データセット
uspto-grants-1979_03
特許番号
US04146558

関連ノート

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