Bis(2-ethylhexyl)amine → Propanamide, N,N-bis(2-ethylhexyl)-2-bromo-

反応式

[CH3:1][CH2:2][CH2:3][CH2:4][CH:5]([CH2:8][NH:9][CH2:10][CH:11]([CH2:14][CH2:15][CH2:16][CH3:17])[CH2:12][CH3:13])[CH2:6][CH3:7].[Br:18][CH:19]([CH3:23])[C:20](Cl)=[O:21]>>[Br:18][CH:19]([CH3:23])[C:20]([N:9]([CH2:8][CH:5]([CH2:6][CH3:7])[CH2:4][CH2:3][CH2:2][CH3:1])[CH2:10][CH:11]([CH2:12][CH3:13])[CH2:14][CH2:15][CH2:16][CH3:17])=[O:21]

参加物

反応物 2

HCID 7791Bis(2-ethylhexyl)amine

HCID 979802-Bromopropanoyl chloride

生成物 1

HCID 533071Propanamide, N,N-bis(2-ethylhexyl)-2-bromo-収率 98%

実験手順

Step A is conducted starting with 2,2′-diethylhexylamine and 2-bromopropionyl chloride and leads to 2-bromo-N,N-bis(2-ethylhexyl)propanamide (Yield: 98%) for which the 1H and 13C NMR characterisations are the following:

出典と根拠

ORDレコード: ord-1afbf282da9749e4968987763070ad89
出典データセット: uspto-grants-2016_09
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US09441285B2

反応ノート

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