Benzoyl chloride → HCID 70477659、化合物

HRID 615309

反応式

HRID 615309 の反応式
[Al+3].[Cl-].[Cl-].[Cl-].[C:5](Cl)(=[O:12])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[C:14]1([CH:20]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[C:21]([OH:23])=[O:22])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>C(Cl)(Cl)(Cl)Cl>[C:5]([C:20]([C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1)([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[C:21]([OH:23])=[O:22])(=[O:12])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1

参加物

5

反応物 3

HCID 7412Benzoyl chlorideHCID 6451240Aluminum(III) ChlorideHCID 220152372-Phenyloctadecanoic acid

生成物 1

HCID 70477659HCID 70477659、化合物収率 40.4%

試薬・触媒・溶媒 1

HCID 5943Carbon Tetrachloride溶媒

実験手順

To a one-liter glass reactor equipped with a mechanical stirrer, condenser, thermometer and addition funnel was charged 300 mls freshly distilled carbon tetrachloride. The flask and its contents were cooled to 0°-5° C. and 40 grams (0.30 mole) AlCl3 added slowly. This was followed by the dropwise addition of 42 grams (0.30 mole) benzoyl chloride and then 26.9 grams (0.075 mole) phenylstearic acid. The mixture was maintained at 0°-5° C. for one hour with agitation and then allowed to warm to room temperature and stirred overnight. A yield of 40.4 percent crude benzoylphenylstearic acid was obtained upon work up of the reaction mixture.

後処理

  1. customTo a one-liter glass reactor equipped with a mechanical stirrer, condenser
  2. additionthermometer and addition funnel
  3. temperatureThe flask and its contents were cooled to 0°-5° C.
  4. temperatureThe mixture was maintained at 0°-5° C. for one hour with agitation

出典と根拠

ORDレコード
ord-a7c93e238e834ea980ec7e1b5bd81082
出典データセット
uspto-grants-1985_02
特許番号
US04499013

関連ノート

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