Acetyl chloride → (1R,S) 1,2,2-trimethyl-1-acetyloxy-3-(2-pentenyl)-cyclopentane

反応式

[CH3:1][C@@:2]1([OH:14])[CH2:6][CH2:5][C@@H:4]([CH2:7][CH:8]=[CH:9][CH2:10][CH3:11])[C:3]1([CH3:13])[CH3:12].[C:15](Cl)(=[O:17])[CH3:16]>>[CH3:1][C@@:2]1([O:14][C:15](=[O:17])[CH3:16])[CH2:6][CH2:5][C@@H:4]([CH2:7][CH:8]=[CH:9][CH2:10][CH3:11])[C:3]1([CH3:13])[CH3:12]

参加物

反応物 2

HCID 6367Acetyl chloride

HCID 70474476(1R,S) 1,2,2-trimethyl-3-(2-pentenyl)-cyclopentanol

生成物 1

HCID 70472830(1R,S) 1,2,2-trimethyl-1-acetyloxy-3-(2-pentenyl)-cyclopentane

実験手順

Using the procedure of Example 15, 2 g of (1R,S) 1,2,2-trimethyl-3-(2-pentenyl)-cyclopentanol and 10 ml of acetyl chloride were reacted to obtain 1.5 g of (1R,S) 1,2,2-trimethyl-1-acetyloxy-3-(2-pentenyl)-cyclopentane.

後処理

customwere reacted

出典と根拠

ORDレコード: ord-b6b851ff54c842bd8a1dfea1ddb85357
出典データセット: uspto-grants-1985_02
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04501687

反応ノート

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