Germanium chloride → Germane, butyltrichloro-
反応式
[Cl:1][Ge:2]([CH2:20][CH2:21][CH2:22][CH3:23])([CH2:16][CH2:17][CH2:18][CH3:19])[Ge:3]([CH2:12][CH2:13][CH2:14][CH3:15])([CH2:8][CH2:9][CH2:10][CH3:11])[CH2:4][CH2:5][CH2:6][CH3:7].[Ge:24]([Cl:28])(Cl)([Cl:26])[Cl:25].C([Ge](CCCC)(CCCC)[Ge](CCCC)(CCCC)CCCC)CCC>>[CH2:4]([Ge:24]([Cl:28])([Cl:26])[Cl:25])[CH2:5][CH2:6][CH3:7].[Cl:1][Ge:2]([CH2:16][CH2:17][CH2:18][CH3:19])([CH2:20][CH2:21][CH2:22][CH3:23])[Ge:3]([CH2:8][CH2:9][CH2:10][CH3:11])([CH2:12][CH2:13][CH2:14][CH3:15])[CH2:4][CH2:5][CH2:6][CH3:7]参加物
5
反応条件
- 温度
- 200 °C
実験手順
Chloropentabutyldigermane having formula 4 of the formula sheet. A mixture of 5.8 g (27.0 mmoles) of germanium tetrachloride and 12.2 g (27.0 mmoles) of hexabutyldigermane was heated for 6.5 hours at 200° C. in a Carius tube. Fractionated distillation yielded 6.0 g of butyltrichlorogermane and 11.2 g of chloropentabutyldigermane; boiling point 130°-131° C./0.06 mm Hg; nD20 =1.4932.