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Potassium Hydroxide → 2-t-Butylazo-2-(t-amylperoxy)-4-methoxy-4-methylpentane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Potassium Hydroxide | HCID 14797 | — |
| 反応物 | tert-Amyl hydroperoxide | HCID 76962 | — |
| 反応物 | 2-t-Butylazo-2-hydroxy-4-methoxy-4-methylpentane | HCID 20367922 | — |
| 反応物 | (E)-1-tert-Butyl-2-(2-chloro-4-methoxy-4-methylpentan-2-yl)diazene | HCID 23344765 | — |
| 生成物 | 2-t-Butylazo-2-(t-amylperoxy)-4-methoxy-4-methylpentane | HCID 20367906 | — |
反応手順
The 2-t-butylazo-2-(t-amylperoxy)-4-methoxy-4-methylpentane was prepared in 97% crude yield from 7.78 grams (0.0331 moles) of 2-t-butylazo-2-chloro-4-methoxy-4-methylpentane, 5.35 grams (0.0464 moles) of 90% t-amyl hydroperoxide and 7.92 grams (0.0353 moles) of 25% potassium hydroxide solution. The procedure was the same as that described in Example XX. The infrared spectrum of the product indicated there was a small amount of 2-t-butylazo-2-hydroxy-4-methoxy-4-methylpentane present in the product.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04075199 |
| 出典データセット | uspto-grants-1978_02 |
| ORD ID | ord-dcfe7a064a2a46a49157193b35d6a997 |
| 出典メモ | uspto-grants-1978_02 |