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Potassium Hydroxide → 1-t-Butylazo-1-(t-amylperoxy)cyclohexane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Potassium Hydroxide | HCID 14797 | — |
| 反応物 | tert-Amyl hydroperoxide | HCID 76962 | — |
| 反応物 | Cyclohexanol, 1-(2-(1,1-dimethylethyl)diazenyl)- | HCID 94561 | — |
| 反応物 | 1-t-Butylazo-1-chlorocyclohexane | HCID 23344784 | — |
| 生成物 | 1-t-Butylazo-1-(t-amylperoxy)cyclohexane | HCID 20367904 | — |
反応手順
The 1-t-butylazo-1-(t-amylperoxy)cyclohexane was prepared in 85% crude yield from 7.5 grams (.037 moles) of 1-t-butylazo-1-chlorocyclohexane, 6.0 grams (.052 moles) of 90% t-amyl hydroperoxide and 9.1 grams (.0407 moles) of 25% potassium hydroxide solution. The procedure was the same as that described in Example XX. The infrared spectrum of the product indicated there was a small amount of 1-t-butylazo-1-hydroxycyclohexane present in the product.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04075199 |
| 出典データセット | uspto-grants-1978_02 |
| ORD ID | ord-5ff53a4a30ca43f7a2b3fd462144ebf0 |
| 出典メモ | uspto-grants-1978_02 |