Methylhydrazine → HCID 178486237、化合物

HRID 616620ノート

反応式

HRID 616620 の反応式
[C:1]([C:3]1[C:4]([C:13]2[N:14]([CH3:21])[C:15]([N+:18]([O-:20])=[O:19])=[CH:16][N:17]=2)=[N:5][N:6]([CH3:12])[C:7]=1N=COC)#[N:2].CNN.[CH3:25][NH:26][NH:27][CH:28]=[N:29]C1N(C)N=C(C2N(C)C([N+]([O-])=O)=CN=2)C=1C#N>C(O)C>[CH3:25][NH:26][NH:27][C:28]([C:7]1[N:6]([CH3:12])[N:5]=[C:4]([C:13]2[N:14]([CH3:21])[C:15]([N+:18]([O-:20])=[O:19])=[CH:16][N:17]=2)[C:3]=1[C:1]#[N:2])=[NH:29]

参加物

5

反応物 3

HCID 6061MethylhydrazineHCID 54162317HCID 54162317、化合物HCID 131710115HCID 131710115、化合物

生成物 1

HCID 178486237HCID 178486237、化合物

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

A mixture of 1.0 g. of methyl N-[4-cyano-1-methyl-3-(1-methyl-5-nitro-2-imidazolyl)pyrazol-5-yl]formimidate, 1 ml. of methyl hydrazine, and 10 ml. of ethanol was stirred at ambient room temperature for about 1 hour. The reaction product mixture was filtered. The solid which was recovered was recrystallized from ethanol to yield product in the form of yellow needles having a melting point of about 232°-234° C. The product was identified by NMR spectrum and elemental analyses as N-[4-cyano-1-methyl-3-(1-methyl-5-nitroimidazol-2-yl)pyrazol-5-yl]formimidic acid, 2-methyl hydrazide.

後処理

  1. additionA mixture of 1.0 g
  2. filtrationThe reaction product mixture was filtered
  3. customThe solid which was recovered
  4. customwas recrystallized from ethanol
  5. customto yield product in the form of yellow needles

出典と根拠

ORDレコード
ord-44769c6300674b0180d258665d8a96e6
出典データセット
uspto-grants-1978_02
特許番号
US04075222

反応ノート

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