(3-Amino-4-methylphenoxy) acetonitrile → (3-Amino-5-chloro-4-methylphenyl) acetonitrile

HRID 618249ノート

反応式

HRID 618249 の反応式
[Cl:1][C:2]1[CH:3]=[C:4]([CH2:12][C:13]#[N:14])[CH:5]=[C:6]([N+:9]([O-])=O)[C:7]=1[CH3:8].NC1C=C(C=CC=1C)OCC#N.CC1C=CC(OCC#N)=CC=1[N+]([O-])=O>>[NH2:9][C:6]1[CH:5]=[C:4]([CH2:12][C:13]#[N:14])[CH:3]=[C:2]([Cl:1])[C:7]=1[CH3:8]

参加物

4

反応物 3

HCID 18789626(3-Amino-4-methylphenoxy) acetonitrileHCID 18789631(4-Methyl-3-nitrophenoxy) acetonitrileHCID 54125367(3-Chloro-4-methyl-5-nitrophenyl) acetonitrile

生成物 1

HCID 54396229(3-Amino-5-chloro-4-methylphenyl) acetonitrile

実験手順

(3-Amino-5-chloro-4-methylphenyl) acetonitrile was prepared from (3-chloro-4-methyl-5-nitrophenyl) acetonitrile in a manner similar to that described in Example 2 for the preparation of (3-amino-4-methylphenoxy) acetonitrile from (4-methyl-3-nitrophenoxy) acetonitrile.

出典と根拠

ORDレコード
ord-258d2d6c98544e9d920ab4dde2e37a2d
出典データセット
uspto-grants-1999_09
特許番号
US05952362

反応ノート

読み込み中…