1-Iodohexane → Methyl 2-hydroxy-4-[7-(1-adamantyl)-6-hexyloxy-2-naphthyl]benzoate

HRID 618483

反応式

HRID 618483 の反応式
[OH:1][C:2]1[CH:11]=[C:10]([C:12]2[CH:21]=[CH:20][C:19]3[C:14](=[CH:15][C:16]([C:23]45[CH2:32][CH:27]6[CH2:28][CH:29]([CH2:31][CH:25]([CH2:26]6)[CH2:24]4)[CH2:30]5)=[C:17]([OH:22])[CH:18]=3)[CH:13]=2)[CH:9]=[CH:8][C:3]=1[C:4]([O:6][CH3:7])=[O:5].I[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39]>>[OH:1][C:2]1[CH:11]=[C:10]([C:12]2[CH:21]=[CH:20][C:19]3[C:14](=[CH:15][C:16]([C:23]45[CH2:24][CH:25]6[CH2:26][CH:27]([CH2:28][CH:29]([CH2:31]6)[CH2:30]4)[CH2:32]5)=[C:17]([O:22][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[CH:18]=3)[CH:13]=2)[CH:9]=[CH:8][C:3]=1[C:4]([O:6][CH3:7])=[O:5]

参加物

3

反応物 2

HCID 125271-IodohexaneHCID 22000320Methyl 2-hydroxy-4-[7-(1-adamantyl)-6-hydroxy-2-naphthyl]benzoate

生成物 1

HCID 22000297Methyl 2-hydroxy-4-[7-(1-adamantyl)-6-hexyloxy-2-naphthyl]benzoate収率 55%

実験手順

Following the procedure of Example 1(a), but reacting 430 mg (1 mmol) of methyl 2-hydroxy-4-[7-(1-adamantyl)-6-hydroxy-2-naphthyl]benzoate with 180 μl (1.2 mmol) of 6-iodohexane, 280 mg (55%) of methyl 2-hydroxy-4-[7-(1-adamantyl)-6-hexyloxy-2-naphthyl]benzoate were obtained.

出典と根拠

ORDレコード
ord-4c1e3c9840214f13b9f2df01de932ffa
出典データセット
uspto-grants-1999_09
特許番号
US05952382

関連ノート

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