化工社化工社 化学情報印刷レポート · 研究参考用
Acetic Acid → Sebacic Acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetic Acid | HCID 176 | — |
| 反応物 | Oxygen | HCID 977 | — |
| 反応物 | Cyclodecane | HCID 9267 | — |
| 反応物 | N-Hydroxyphthalimide | HCID 10665 | — |
| 生成物 | Sebacic Acid | HCID 5192 | 48% |
| 生成物 | Cyclodecanone | HCID 73918 | 39% |
| 生成物 | Sebacil | HCID 96839 | 5% |
反応手順
A mixture of 1.40 grams (10 millimoles) of cyclodecane, 0.13 gram (0.8 millimole) of N-hydroxyphthalimide, 0.015 gram (0.06 millimole) of Co(AA)2 and 25 milliliters of acetic acid was stirred in an oxygen atmosphere at a temperature of 100° C. for six hours. As a result, cyclodecane was transformed into cyclodecanone (yield 39%), sebacic acid (yield 48%) and cyclodecanedione (yield 5%) with a transformation rate of 96%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05958821 |
| 出典データセット | uspto-grants-1999_09 |
| ORD ID | ord-dce6f015c3404477a537c72a080277ea |
| 出典メモ | uspto-grants-1999_09 |