関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Acetic Acid | HCID 176 | — |
| 反応物 | N-Hydroxyphthalimide | HCID 10665 | — |
| 反応物 | 1,3-Adamantanediol | HCID 573829 | — |
| 生成物 | 1,3,5,7-Tetrahydroxyadamantane | HCID 820093 | 62% |
| 生成物 | 1,3,5-Adamantanetriol | HCID 9899022 | 37% |
反応手順
A mixture of 1.68 grams (10 millimoles) of 1,3-adamantanediol, 0.13 gram (0.8 millimole) of N-hydroxyphthalimide, 0.015 gram (0.06 millimole) of Co(AA)2 and 25 milliliters of acetic acid was stirred under an oxygen atmosphere at a temperature of 95° C. for 6 hours. Thus, 1,3-adamantanediol was transformed, with a transformation rate of 99%, into 1,3,5-adamantanetriol (selectivity for 1,3-adamantanediol 37%, yield 37%) and 1,3,5,7-adamantanetetraol (selectivity for 1,3-adamantanediol 62%, yield 62%). The selectivity for the alcohols was 99%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05958821 |
|---|
| 出典データセット | uspto-grants-1999_09 |
|---|
| ORD ID | ord-712bd5ea89924bcdae091b67af9d7139 |
|---|
| 出典メモ | uspto-grants-1999_09 |
|---|
