化工社化工社 化学情報印刷レポート · 研究参考用
Oxygen → 2-Pinanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oxygen | HCID 977 | — |
| 反応物 | Pinane | HCID 10129 | — |
| 反応物 | N-Hydroxyphthalimide | HCID 10665 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | 2-Pinanol | HCID 10128 | 82% |
反応手順
To 25 milliliters of acetonitrile were added 1.38 grams (10 millimoles) of pinane, 0.13 gram (0.8 millimole) of N-hydroxyphthalimide and 0.015 gram (0.06 millimole) of Co(AA)2, and the resultant mixture was stirred in an oxygen atmosphere at a temperature of 100° C. for six hours. Pinane was transformed into 2-pinanol (selectivity for pinane 91%, yield 82%) with a transformation rate of 90%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05958821 |
| 出典データセット | uspto-grants-1999_09 |
| ORD ID | ord-2d1f307dec764a8ead7ab279d21b9f11 |
| 出典メモ | uspto-grants-1999_09 |