化工社化工社 化学情報印刷レポート · 研究参考用
Dimethylamine → Phosphonic acid, P,P'-ethenylidenebis-, P,P,P',P'-tetrakis(1-methylethyl) ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dimethylamine | HCID 674 | — |
| 反応物 | Formaldehyde | HCID 712 | — |
| 反応物 | Tetraisopropyl methylenediphosphonate | HCID 74266 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | Phosphonic acid, P,P'-ethenylidenebis-, P,P,P',P'-tetrakis(1-methylethyl) ester | HCID 4488726 | 24.3% |
反応手順
11.95 g (34.7 mmol) of tetraisopropyl methylenebisphosphonate, 5.2 g (173.5 mmol) of paraformaldehyde and 2.54 g (34.7 mmol) of dimethylamine are combined with the same reactants and at the same conditions as described above in Example I. This mixture is then refluxed for 117 hours. After the methanol has been eliminated as described above in Example I, 3.0 g of tetraisopropyl ethenylidenebisphosphonate is produced as a clear liquid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04820698 |
| 出典データセット | uspto-grants-1989_04 |
| ORD ID | ord-0de123eb8d014e9995f2781281d67cdd |
| 出典メモ | uspto-grants-1989_04 |