化工社化工社 化学情報印刷レポート · 研究参考用
Isobutylene → 4-Isobutenylcyclohexene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Isobutylene | HCID 8255 | — |
| 反応物 | Cyclohexene, 4,4'-(1,2-ethenediyl)bis- | HCID 86582 | — |
| 生成物 | 4-Vinyl-1-cyclohexene | HCID 7499 | — |
| 生成物 | 4-Isobutenylcyclohexene | HCID 21245550 | 31.3% |
反応手順
13.1 g of the catayst prepared in Example 17 was charged into a steel reactor under a blanket of nitrogen. To this was added 8.4 g of 1,2-dicyclohex-4-enyl ethylene and 27 g of isobutene. The reactor was sealed and rocked. After 1 hour at ambient temperature, the products were analysed. 3.7% of the 1,2-dicyclohex-4-vinyl ethylene was converted affording dismutation products with the following selectivities 31.3% 4-isobutenylcyclohexene and 69.% 4-vinylcyclohexene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04822937 |
| 出典データセット | uspto-grants-1989_04 |
| ORD ID | ord-505e683730c14950a37204dc2f5928f4 |
| 出典メモ | uspto-grants-1989_04 |