化工社化工社 化学情報印刷レポート · 研究参考用
Water → Acetophenone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Cumene | HCID 7406 | — |
| 反応物 | 1,4-Diisopropylbenzene | HCID 7486 | — |
| 反応物 | 2-Phenyl-2-propanol | HCID 12053 | — |
| 生成物 | Acetophenone | HCID 7410 | — |
| 生成物 | Cumen hydroperoxide | HCID 53627471 | — |
反応手順
Using 79.9 g (0.665 mole) of cumene in lieu of p-diisopropylbenzene, oxidation was carried out in the same apparatus and under the same conditions as those employed in Example 1. The reaction product obtained subsequent to its water washing and drying was an oily matter whose weight was 79.6 g. According to results of a high-performance liquid chromatographic analysis, the oily matter was found to contain 3.1 g (0.026 mole; conversion: 96.1%) of cumene and 75.3 g (0.553 mole; yield: 83.2 mole %) of dimethylphenylcarbinol. Acetophenone or cumene hydroperoxide was not formed practically.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04825007 |
| 出典データセット | uspto-grants-1989_04 |
| ORD ID | ord-2fb7bffb1d064be3b513c787f38a15b1 |
| 出典メモ | uspto-grants-1989_04 |