Cobaltous nitrate hexahydrate → HCID 86742448、化合物

HRID 622653

反応式

HRID 622653 の反応式
[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[CH:6]=[CH:7][C:8]3[CH:9]=[CH:10][C:11]([CH3:16])=[N:12][C:13]=3[C:14]=2[N:15]=1.O.O.O.O.O.O.[N+]([O-])([O-])=O.[Co+2:27].[N+]([O-])([O-])=O.[Cl:32]([O-:36])(=[O:35])(=[O:34])=[O:33].[Na+]>O.CO>[Cl:32]([O-:36])(=[O:35])(=[O:34])=[O:33].[Co+3:27].[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[C:14](=[C:13]3[C:8](=[CH:7][CH:6]=2)[CH:9]=[CH:10][C:11]([CH3:16])=[N:12]3)[N:15]=1.[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[C:14](=[C:13]3[C:8](=[CH:7][CH:6]=2)[CH:9]=[CH:10][C:11]([CH3:16])=[N:12]3)[N:15]=1.[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[C:14](=[C:13]3[C:8](=[CH:7][CH:6]=2)[CH:9]=[CH:10][C:11]([CH3:16])=[N:12]3)[N:15]=1.[Cl:32]([O-:36])(=[O:35])(=[O:34])=[O:33].[Cl:32]([O-:36])(=[O:35])(=[O:34])=[O:33]

参加物

5

反応物 3

HCID 24821Cobaltous nitrate hexahydrateHCID 652372,9-Dimethyl-1,10-phenanthrolineHCID 522606Sodium Perchlorate

生成物 1

HCID 86742448HCID 86742448、化合物収率 86%

試薬・触媒・溶媒 1

HCID 22242641Methanol--water (1/1)溶媒

反応条件

温度
4 °C

実験手順

Neocuproine (1.00 g, 0.00480 mole) and cobalt (II) nitrate hexahydrate (0.466 g, 0.00160 mole) were dissolved in 30 ml 2:1 water-methanol with stirring in a 60° water bath. Sodium perchlorate solution (3.5 ml 1.5M) was added rapidly with stirring. A flaky pink precipitate was formed immediately. After cooling at 4° C., the product was collected by vacuum filtration and dried in vacuum. Yield=86%. IR: 2800-3700, 1630, 1600, 1570, 1500, 1425, 1390, 1360, 1300, 1030-1150, 860, 730, 625 cm-1.

後処理

  1. stirringwith stirring
  2. customA flaky pink precipitate was formed immediately
  3. filtrationthe product was collected by vacuum filtration
  4. customdried in vacuum

出典と根拠

ORDレコード
ord-8730f0ad45a64c63af98c72162520657
出典データセット
uspto-grants-1988_09
特許番号
US04772563

関連ノート

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