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Bis(eta-cyclopentadienyl) iron → Mesitylene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Bis(eta-cyclopentadienyl) iron | HCID 7611 | — |
| 反応物 | Mesitylene | HCID 7947 | — |
| 反応物 | Aluminum(III) Chloride | HCID 6451240 | — |
| 触媒 | Zirconium chloride (ZrCl4), (T-4)- | HCID 9856075 | — |
| 生成物 | Mesitylene | HCID 7947 | — |
| 生成物 | HCID 178418685 | HCID 178418685 | — |
反応手順
In accordance with the procedure of Example 4, 10 g (0.043 mol) of ZrCl4 are added at 60° C. under argon over the course of 1 hour and 10 minutes to a stirred mixture of 60 ml of mesitylene, 8 g (0.043 mol) of ferrocene and 5.7 g (0.043 mol) of sublimed AlCl3. Working up is effected as in Example 4, affording 20.1 g (83.4% of theory) of crude (η6 -mesitylene)-η5 -(cyclopentadienyl)-iron(II) tetrapnenylborate.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05247107 |
| 出典データセット | uspto-grants-1993_09 |
| ORD ID | ord-6e509896da094dc58fef5e22f2f94349 |
| 出典メモ | uspto-grants-1993_09 |