関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Diphenyl Ether | HCID 7583 | — |
| 反応物 | Triphenylbismuth | HCID 11774 | — |
| 反応物 | Trioctylphosphine | HCID 20851 | — |
| 反応物 | Trioctylphosphine oxide | HCID 65577 | — |
| 反応物 | Oleic Acid | HCID 445639 | — |
| 反応物 | Oleylamine | HCID 5356789 | — |
| 反応物 | Selenium | HCID 6326970 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 溶媒 | 1-Octadecene | HCID 8217 | — |
| 溶媒 | N-methyl-2-pyrrolidone | HCID 13387 | — |
| 生成物 | Di-n-octylphosphinic acid | HCID 99411 | — |
反応手順
Materials. 1-methyl-2-pyrrolidinone (99.5%, Aldrich), 1-octadecene (90%, Aldrich), acetonitrile (99.9%, Fisher Chemical), triphenylbismuth (99%, Strem), CdO (99.5%, Aldrich), diphenyl ether (99%, Aldrich), methanol (ACS grade, VWR), oleic acid (90%, Aldrich), oleylamine (70% Aldrich), selenium (99.99%, Strem), trioctylphosphine (90%, Aldrich), trioctylphosphine oxide (99%, Strem), toluene (ACS grade, VWR). 0.2M Se-ODE was prepared by dissolving selenium powder in 1-octadecene at 200° C. for 2 hr under inert atmosphere according to the procedure by Bullen et al.[42]; trioctylphosphine oxide (TOPO) was recrystallized from acetonitrile prior to use; di-n-octylphosphinic acid (DOPA) was synthesized according to the procedure reported by Wang et al.[1]; a stock suspension of 2 mM triphenylbismuth (BiPh3) in 1-octadecene was prepared in advance.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US09306110B2 |
|---|
| 出典データセット | uspto-grants-2016_04 |
|---|
| ORD ID | ord-9c3a268df10549b2be3b6aeb3d49fbb1 |
|---|
| 出典メモ | uspto-grants-2016_04 |
|---|
