化工社化工社 化学情報印刷レポート · 研究参考用
Glucaric Acid → Adipic Acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Glucaric Acid | HCID 33037 | — |
| 反応物 | Galactaric acid | HCID 3037582 | — |
| 触媒 | Rhenium | HCID 23947 | — |
| 生成物 | Adipic Acid | HCID 196 | — |
反応手順
Further, as described above, the starting material (glucaric acid or galactaric acid), rhenium catalyst, and acid catalyst are added to the reaction solvent, and reacted together at a proper temperature for a proper reaction time, then separated and purified with a conventional method (e.g., purification with silica column) to obtain glucaric acid ester or galactaric acid ester as an intermediate of adipic acid. In one embodiment, the reaction temperature ranges from 100 to 200° C., and the reaction time is 12 to 24 hours.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09447012B2 |
| 出典データセット | uspto-grants-2016_09 |
| ORD ID | ord-e4d92eb81e1047428d952ffc9a9ab295 |
| 出典メモ | uspto-grants-2016_09 |